Посилання:Anisotropic g factors of the tetragonal Cu²⁺ monomer in Tl-2223 superconductor / Zhi-Hong Zhang, Shao-Yi Wu, Min-Quan Kuang, and Chang-Chun Ding // Физика низких температур. — 2015. — Т. 41, № 3. — С. 233-234. — Бібліогр.: 15 назв. — англ.
Підтримка:This work was financially supported by “the National Natural Science Foundation of China” under granted No. 11404052, “the Sichuan Province Academic and Technical Leaders Support Fund” under granted No. Y02028023601015, “the Fundamental Research Funds for the Central Universities” under granted No. ZYGX2012YB018 and “the Fundamental Research Funds for the Central Universities” under granted No. ZYGX2012J046.
The gyromagnetic factors of the Cu²⁺ monomer in Tl-2223 superconductor are quantitatively investigated from the perturbation formulas of these factors for a 3d⁹ ion in a tetragonally elongated octahedron. The local tetragonal distortion of the system is attributable to the axial elongation along c axis, corresponding to the five-fold coordinated Cu²⁺(2) site with almost 30% longer Cu–O bond length for the apical oxygen as compared to the four planar ones. The significant anisotropic behaviors of the EPR spectra perpendicular to and parallel with the ab (CuO₂) layers are analyzed on the basis of the local tetragonal elongation.