Анотація:
The complete Raman spectra of a single crystal of LiNiPO₄ for a wide temperature range are reported. Among the 36 Raman-active modes predicted by group theory, 33 have been detected. The analysis of the spectra in terms of internal modes of the (PO₄)³⁻ group and of external modes is done with success. Besides, the multiphonon Raman scattering is discussed. Low-frequency lines, observed in the antiferromagnetic phase, are assigned to magnon scattering and are discussed briefly.