Посилання:UV-VUV synchrotron radiation spectroscopy of NiWO₄ / A. Kuzmin, V. Pankratov, A. Kalinko, A. Kotlov, L. Shirmane, A.I. Popov // Физика низких температур. — 2003. — Т. 42, № 7. — С. 694-698. — Бібліогр.: 47 назв. — англ.
Підтримка:This work was supported by Latvian Science Council
Grant No. 187/2012. The experiments at DESY leading to
these results have received funding from the European
Community’s Seventh Framework Programme (FP7/2007-
2013) under grant agreement No. 226716. V.P. acknowledges
the financial supports from Oulu University Strategic
Funding and Research Council for Natural Sciences of the
Academy of Finland.
Photoluminescence and excitation spectra of microcrystalline and nanocrystalline nickel tungstate (NiWO₄) were measured using UV-VUV synchrotron radiation source. The origin of the bands is interpreted using comparative analysis with isostructural ZnWO₄ tungstate and based on the results of recent first-principles band structure calculations. The influence of the local atomic structure relaxation and of Ni²⁺ intra-ion d–d transitions on the photoluminescence band intensity are discussed.