Посилання:Structure and magnetism of copper substituted cobalt ludwigite Co₃O₂BO₃ / N.B. Ivanova, N.V. Kazak, Yu.V. Knyazev, D.A. Velikanov, A.D. Vasiliev, L.N. Bezmaternykh, M.S. Platunov // Физика низких температур. — 2013. — Т. 39, № 8. — С. 913–918. — Бібліогр.: 15 назв. — англ.
Підтримка:The study was supported by the Russian Foundation for Basic Research (projects 12–02–00175-a, 12–02–90410-Ukr-a, 12–02–31543-mol-a, 13–02–00958), Leading Scientific Schools NSch 1044.2012.2.
The single crystals Co₃O₂BO₃ with partial (4%) substitution of Co by Cu ions were synthesized by the flux technique. X-ray diffraction and magnetic properties investigations were carried out. The x-ray diffraction meas-urements have shown that Cu clearly prefers only one from four nonequivalent crystallographic positions with the smallest electric field gradient. The ferrimagnetic ordering near TN = 43 K and high magnetic hardness in this magnetic phase are similar to Co₃O₂BO₃. The small reduction of the effective magnetic moment was revealed under copper substitution.