Посилання:Electronically induced modification of thin layers
on surfaces / U. Bauer, S. Neppl, D. Menzel, P. Feulner, A. Shaporenko, M. Zharnikov // Физика низких температур. — 2007. — Т. 33, № 6-7. — С. 680-688. — Бібліогр.: 28 назв. — англ.
Підтримка:We thank D.L. Allara for supporting us with the substance
for the nitrile terminated SAMs, K.L. Kostov, N.
Faradzhev and T.E. Madey for helpful discussions, and
M. Grunze for support of the SAM related experiments.
Help during the experiments by K. Eberle, R. Schneider,
and the staff of BESSY, in particular O. Schwarzkopf,
H. Pfau, and W. Braun, is gratefully acknowledged. The
investigations have been supported by the Deutsche
Forschungsgemeinschaft (Fe 347/1-3), by the German
BMBF (05 KS4VHA/4 and 05 ES3XBA/5), and by the
German Fonds der Chemischen Industrie.
Interactions of thermally and electronically stimulated reactions in thin layers on surfaces are investigated.
For self-assembled monolayers, thermal activation promotes many processes primarily induced by
electronic excitations. We demonstrate that the film temperature is an important parameter for steering these
reactions towards different final products. Using chemisorbed water on Ru(001) as an example, we investigate
how the products of an irradiation induced reaction catalyze thermally stimulated dissociation of water
molecules.