Посилання:Isochoric thermal conductivity of solid nitrogen / V.A. Konstantinov, V.G. Manzhelii, V.P. Revyakin, V.V. Sagan // Физика низких температур. — 2005. — Т. 31, № 5. — С. 553-557. — Бібліогр.: 12 назв. — англ.
Підтримка:This study was supported by the Ukrainian Ministry
of Education and Science, Project (7/286-2001
«Novel quantum and unharmonic effects in mixtures
of cryocrystals».
The isochoric thermal conductivity of solid nitrogen has been investigated on four samples of
different densities in the temperature interval from 20 K to the onset of melting. In α-N₂ the
isochoric thermal conductivity exhibits a dependence weaker than Λ1/T; in β-N₂ it increases
slightly with temperature. The experimental results are discussed within a model in which the heat
is transported by low-frequency phonons or by «diffusive» modes above the mobility edge. The
growth of the thermal conductivity in β-N₂ is attributed to the decreasing «rotational» component
of the total thermal resistance, which occurs as the rotational correlations between the neighboring
molecules become weaker.