Наукова електронна бібліотека
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періодичних видань НАН України
Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium
Репозиторій DSpace/Manakin
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Cathodic corrosion: Part 1. Mechanism of corrosion via formation of metal anions in aqueous medium
Тема:
К 75-летию со дня рождения И. К. Янсона
Інший ID:
PACS: 82.45.Aa, 82.45.Bb, 82.30.–b
Посилання:
Cathodic corrosion: Part 1. Mechanism of corrosion
via formation of metal anions in aqueous medium / Yu.I. Yanson, A.I. Yanson // Физика низких температур. — 2013. — Т. 39, № 3. — С. 390–398. — Бібліогр.: 46 назв. — англ.
Підтримка:
A.I.Y. and Yu.I.Y. acknowledge the Dutch NWO vidi
grant and STW Valorization grant (project 12572), respectively.
We thank F. Tichelaar (TU Delft) for TEM analysis,
T. Oosterkamp for providing generous SEM access, P. Rodriguez
and N. Garcia-Araez for useful discussions and suggestions.
Дата:
2013
Переглядів:
784
Завантажень:
688
Анотація:
In this paper we describe an unusual electrochemical phenomenon, namely cathodic corrosion of platinum.
We show that all existing models of cathodic corrosion are inconsistent with our experimental observations.
Therefore, we present a new model of cathodic corrosion, which is based on the assumption that metal anions are
formed at the electrode surface during the corrosion process. These anionic species function as precursors for the
formation of the final product of cathodic corrosion–metal nanoparticles.
