It is shown that the adsorption of HCl molecules at the surface of ice increases,
if the HCl binding energy increases with the distortion amplitude
of the oxygen sites of ice. At the same time, the adsorption stimulates ...
A simple electrolyte in a polar solvent is modelled by a mixture of polar hard
spheres and equal diameter charged hard spheres with the possibility of
ionic dimerization. The analytical solution of the associative mean ...
The recently proposed scaled particle theory SPT2 approach to the description of three-dimensional hard sphere fluids in random porous media is extended for one- and two-dimensional cases. Analytical expressions for the ...
Review: J.Barthel, H.Krienke, W.Kunz. Physical Chemistry of Electrolyte Solutions: Modern Aspects. Steinkopff, Darmstadt and Springer, New York, 1998, 401 p.)
The density, charge, polarization and potential profiles of a simple model
of an associative electrolyte are studied in an associative mean spherical
approximation (AMSA). The limits of the full association and complete ...
A well-known cluster expansion, which leads to virial expansion for the free energy of low density systems, is
modified in such a way that it becomes applicable to the description of condensed state of matter. To this ...
The role of adsorbate clustering in increasing the adsorption on crystalline
surfaces is analyzed in terms of the lattice gas model combined with the
results of the associative theory. The effect of the cluster size and ...
di Caprio, D.; Holovko, M.F.; Badiali, J.P.(Condensed Matter Physics, 2003)
In this paper we study the effect of the interaction potential in a liquid where
there is an equilibrium of association of a molecule into dimers. We use a
field theory where the fields represent the densities of the ...
The traditional formalism in liquid state theory based on the calculation of the pair distribution function is generalized and reviewed for nematic fluids. The considered approach is based on the solution of orientationally ...
The solution of the associative mean-spherical approximation for ion- dipolar system is reinvestigated and
expressed in terms of only five parameters. Three of them have counterparts in the case without association,
and ...
The scaled particle theory is developed for the description of thermodynamical properties of a mixture of hard
spheres and hard spherocylinders. Analytical expressions for free energy, pressure and chemical potentials
are ...
A short review of theoretical results on the Langmuir-Hinschelwood and
Eley-Rideal reaction schemes is presented. It is shown that the rates of elementary processes at the surface are coupled through the bulk properties
of ...
An extension of the product-reactant Ornstein-Zernike approach (PROZA)
for the fluid of flexible star molecules is proposed and the corresponding
version of the mean spherical approximation (MSA), the so-called polymer
MSA ...
The scaled particle theory (SPT) approximation is applied for the study of the influence of a porous medium on
the isotropic-nematic transition in a hard spherocylinder fluid. Two new approaches are developed in order ...
Selective adsorption from binary polymer mixtures on a crystalline surface
is studied in terms of the lattice gas model in conjunction with the results
of the association theory. An interplay of the selectivity and the ...
Hard wall confined fluid with Yukawa potential of interaction is considered. A solution of the inhomogeneous
Ornstein-Zernike equation for the pair correlation function is obtained. The expression for the particle ...
Ionic association in electrolyte solutions is investigated in the framework of
chemical models. The associative mean spherical approximation (AMSA)
for electrolyte theory is reviewed. It is shown that AMSA in combination
with ...
The specific sum rules in the theory of electrical double layer are formulated
as the consequence of contact theorem. They concern the correlation
functions of electrolyte when one ion is located on the surface. A ...
Recent development of the multi-density integral equation approach and
its application to the statistical mechanical modelling of a different type of
association and clusterization in liquids are reviewed. The effects ...
Holovko, M.F.(Вопросы атомной науки и техники, 2001)
Recent development of the multi-density integral equation approach and its application to the statistical mechanical modelling of a different type of association and clusterization in liquids and solutions are reviewed. ...