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dc.contributor.author |
Ковтун, Г.А. |
|
dc.contributor.author |
Пустарнакова, Г.Ф. |
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dc.date.accessioned |
2009-07-14T13:13:14Z |
|
dc.date.available |
2009-07-14T13:13:14Z |
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dc.date.issued |
2001 |
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dc.identifier.citation |
Кластер кобальта Co3(μ3–CC6H4NH2)(CO)9 в катализе обрыва цепей окисления циклогексадиена-1,3 / Г.А. Ковтун, Г.Ф. Пустарнакова // Катализ и нефтехимия. — 2001. — № 8. — С. 23-25. — Бібліогр.: 6 назв. — рос. |
en_US |
dc.identifier.uri |
http://dspace.nbuv.gov.ua/handle/123456789/4046 |
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dc.description.abstract |
The catalysis of oxidation chain breaking of cyclohexadiene-1,3 by clusters of cobaltous Co3(μ3–CC6H4NH2)(CO)9 has been revealed at 50 °С. The mechanism of catalysis realized in alternating reactions of radicals НОО with NH2- and N.H-group of the μ3–coordinated ligand: HOO+ μ3CC6H4NH2 → H2O2 + μ3CC6H4N .H CH3-p; (1); HOO+ μ3CC6H4NH → O2 + μ3CC6H4NH2 (2) has been substantiated. |
en_US |
dc.description.abstract |
The catalysis of oxidation chain breaking of cyclohexadiene-1,3 by clusters of cobaltous Co3(μ3–CC6H4NH2)(CO)9 has been revealed at 50 °С. The mechanism of catalysis realized in alternating reactions of radicals НОО with NH2- and N.H-group of the μ3–coordinated ligand: HOO+ μ3CC6H4NH2 → H2O2 + μ3CC6H4N .H CH3-p; (1); HOO+ μ3CC6H4NH → O2 + μ3CC6H4NH2 (2) has been substantiated. |
en_US |
dc.description.abstract |
The catalysis of oxidation chain breaking of cyclohexadiene-1,3 by clusters of cobaltous Co3(μ3–CC6H4NH2)(CO)9 has been revealed at 50 °С. The mechanism of catalysis realized in alternating reactions of radicals НОО with NH2- and N.H-group of the μ3–coordinated ligand: HOO+ μ3CC6H4NH2 → H2O2 + μ3CC6H4N .H CH3-p; (1); HOO+ μ3CC6H4NH → O2 + μ3CC6H4NH2 (2) has been substantiated. |
en_US |
dc.language.iso |
ru |
en_US |
dc.publisher |
Інститут бiоорганiчної хiмiї та нафтохiмiї НАН України |
en_US |
dc.title |
Кластер кобальта Co3(μ3–CC6H4NH2)(CO)9 в катализе обрыва цепей окисления циклогексадиена-1,3 |
en_US |
dc.title.alternative |
Кластер кобальту Co3(μ3–CC6H4NH2)(CO)9 у каталізі обриву ланцюгів окиснення циклогексадієну-1,3 |
en_US |
dc.title.alternative |
Сluster of cobaltous Co3(μ3–CC6H4NH2)(CO)9 in catalysis of oxidation chain breaking of cyclohexadiene-1,3 |
en_US |
dc.type |
Article |
en_US |
dc.status |
published earlier |
en_US |
dc.identifier.udc |
547.113: 541.124 |
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