Ionization and hydrolysis of dinitrogen pentoxide in low-temperature solids

dc.contributor.author	Agreiter, J.
dc.contributor.author	Frankowski, M.
dc.contributor.author	Bondybey, V.E.
dc.date.accessioned	2018-01-15T13:26:10Z
dc.date.available	2018-01-15T13:26:10Z
dc.date.issued	2001
dc.identifier.citation	Ionization and hydrolysis of dinitrogen pentoxide in low-temperature solids / J.Agreiter, M.Frankowski, V.E. Bondybey // Физика низких температур. — 2001. — Т. 27, № 9-10. — С. 1202-1207. — Бібліогр.: 19 назв. — англ.	uk_UA
dc.identifier.issn	0132-6414
dc.identifier.other	PACS: 78.30.-j
dc.identifier.uri	http://dspace.nbuv.gov.ua/handle/123456789/129024
dc.description.abstract	Solid layers of interest for the chemistry of polar stratospheric clouds were investigated. Mixtures of covalent N₂O₅ and water in various molar ratios are deposited from vapor phase on a cold 12 K substrate. By repeatedly recording Fourier transform infrared spectra of the samples during gradual warm up to 200 K over a period of several hours the hydrolysis process can be followed. At each concentration the process is found to proceed in several distinct steps with sharp temperature thresholds. In samples containing only small amounts of water the covalent N₂O₅ is first around 110 K converted to an ionic nitronium nitrate, and only in a subsequent step NO₂+NO₃- reacts to nitric acid.	uk_UA
dc.language.iso	en	uk_UA
dc.publisher	Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України	uk_UA
dc.relation.ispartof	Физика низких температур
dc.subject	Статьи, посвященные столетию со дня рождения Л. В. Шубникова	uk_UA
dc.title	Ionization and hydrolysis of dinitrogen pentoxide in low-temperature solids	uk_UA
dc.type	Article	uk_UA
dc.status	published earlier	uk_UA