From optical spectra to phase diagrams — the binary mixture N2–CO

Abstract

We investigated the T–c% phase diagram of the binary system N2–CO. From changes in IR spectra of all kinds of mode excitations (phonons, vibrons) we were able to determine the temperature of phase transitions (solid–solid, solid–liquid). The improvements in comparison to structural investigations by x-rays or electrons are the following: sample growing and handling with perfect optical and thermodynamic quality; determination of actual concentration (N2)x(CO)y from optical spectra; reduction of thermal hysteresis by careful cooling–heating cycles of the samples.