Ionic chromophores Xe⁺p  (p≤ 4) in multishell rare-gas clusters Xem(NF₃)kNe₇₅₀₀ (m, k ≤ 100) studied with fluorescence spectroscopy

Ionic chromophores Xe⁺p (p≤ 4) in multishell rare-gas clusters Xem(NF₃)kNe₇₅₀₀ (m, k ≤ 100) studied with fluorescence spectroscopy

Kanaev, A. ; Museur, L. ; Laarmann, T. ; Muller, T.

Тема: Clusters

Інший ID: PACS: 36.40.–c, 36.40.Vz, 33.50.Dq

URI: http://dspace.nbuv.gov.ua/handle/123456789/120892

Посилання: Ionic chromophores Xe⁺p (p≤ 4) in multishell rare-gas clusters Xem(NF₃)kNe₇₅₀₀ (m, k ≤ 100) studied with fluorescence spectroscopy / A. Kanaev, L. Museur, T. Laarmann, T. Muller // Физика низких температур. — 2006. — Т. 32, № 11. — С. 1426–1433. — Бібліогр.: 28 назв. — англ.

Підтримка: This work was supported by the IHP-Contract HPRI-CT-1999-00040 of the European Commission.

Дата: 2006

Завантажень: 501

Ionic chromophores Xe⁺p (p≤ 4) in multishell rare-gas clusters Xem(NF₃)kNe₇₅₀₀ (m, k ≤ 100) studied with fluorescence spectroscopy

Анотація:

We have studied fluorescence spectra of small Xem and Xem(NF3)k clusters (m, k ≤ 10²) embedded in large host Ne₇₅₀₀ clusters, excited with SR excitation in the VUV spectral region above the Xe⁺(²P₁/₂) atomic limit. The IR emission bands due to ionic chromophores Xe⁺p (p = 2, 3, 4) as well as UV (B–X) and visible (C–A) bands due to desorbed Xe⁺F⁻– excimer molecules have been observed. The triatomic Xe₂F excimer emission has only been observed under low-energy excitation close to the lowest xenon exciton absorption band. A competition between ionic and charge-transfer reaction channels is followed as a function of the cluster sizes m and k.

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