Посилання:The radiation-induced chemistry in solid xenon matrices / V.I. Feldman, A.V. Kobzarenko, A.Y. Orlov, F.F. Sukhov // Физика низких температур. — 2012. — Т. 38, № 8. — С. 961-969. — Бібліогр.: 63 назв. — англ.
Підтримка:The studies in our laboratory were continuously supported
by the Division of Chemistry of The Russian Academy
of Sciences under program No. 1.
The paper presents an overview of recent studies on the radiation-chemical transformations of guest molecules
in solid xenon induced by fast electrons and x-ray irradiation. Specific features of the experimental approach
based on combination of matrix isolation IR and EPR spectroscopy are briefly outlined (with particular
impact on using monoisotopic and isotopically enriched xenon matrices). The results reveal rich and diverse radiation-induced
chemistry in solid xenon, which is considered in the following major aspects: (1) matrix-induced
and matrix assisted transformations of the primary guest radical cations; (2) production and dynamics of hydrogen
atoms; (3) formation of xenon hydrides. Finally, preliminary results on the radiation-induced generation of
oxygen atoms and ions in solid xenon are presented.